Ta có: \(n_{H_2}=\dfrac{1,344}{22,4}=0,06\left(mol\right)\)

PTHH: 

2Al + 6HCl ---> 2AlCl₃ + 3H₂ (1)

Al₂O₃ + 6HCl ---> 2AlCl₃ + 3H₂ (2)

Theo PT₍₁₎: \(n_{Al}=\dfrac{2}{3}.n_{H_2}=\dfrac{2}{3}.0,06=0,04\left(mol\right)\)

\(\Rightarrow m_{Al}=0,04.27=1,08\left(g\right)\)

\(\Rightarrow m_{Al_2O_3}=2,1-1,08=1,02\left(g\right)\)

\(\Rightarrow n_{Al_2O_3}=\dfrac{1,02}{102}=0,01\left(mol\right)\)

Theo PT₍₁₎: \(n_{HCl}=3.n_{Al}=3.0,04=0,12\left(mol\right)\)

Theo PT₍₂₎: \(n_{HCl}=6.n_{Al_2O_3}=6.0,01=0,06\left(mol\right)\)

\(\Rightarrow m_{HCl}=\left(0,06+0,12\right).36,5=6,57\left(g\right)\)

Ta có: \(C_{\%_{HCl}}=\dfrac{6,57}{m_{dd_{HCl}}}.100\%=7,3\%\)

\(\Rightarrow m_{dd_{HCl}}=90\left(g\right)\)

a) \(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)

PTHH: 2Al + 6HCl --> 2AlCl₃ + 3H₂

             0,4------------>0,4---->0,6

=> \(V_{H_2}=0,6.22,4=13,44\left(l\right)\)

b) 

\(m_{AlCl_3}=0,4.133,5=53,4\left(g\right)\)

c)

PTHH: CuO + H₂ --t^o--> Cu + H₂O

                       0,6------>0,6

=> m_Cu = 0,6.64 = 38,4 (g)

`n_[Al]=[10,8]/27=0,4(mol)`

`2Al + 6HCl -> 2AlCl_2 + 3H_2 \uparrow`

`0,4`                              `0,4`     `0,6`      `(mol)`

`a)V_[H_2]=0,6.22,4=13,44(l)`

`b)m_[AlCl_2]=0,4.98=39,2(g)`

`c)`

`H_2 + CuO` $\xrightarrow{t^o}$ `Cu + H_2 O`

`0,4`                     `0,4`                 `(mol)`

`=>m_[Cu]=0,4.64=25,6(g)`

\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\ n_{HCl}=\dfrac{24,6375}{36,5}=0,675\left(mol\right)\)

PTHH: 2Al + 6HCl ---> 2AlCl₃ + 3H₂

LTL: \(\dfrac{0,2}{2}< \dfrac{0,675}{3}\rightarrow\) HCl dư

Theo pthh: \(\left\{{}\begin{matrix}n_{HCl\left(pư\right)}=3n_{Al}=3.0,2=0,6\left(mol\right)\\n_{H_2}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}.0,2=0,3\left(mol\right)\\n_{AlCl_3}=n_{Al}=0,2\left(mol\right)\end{matrix}\right.\)

\(\rightarrow\left\{{}\begin{matrix}m_{AlCl_3}=0,2.133,5=26,7\left(g\right)\\m_{HCl\left(dư\right)}=\left(0,675-0,5\right).36,5=2,7375\left(g\right)\\V_{H_2}=0,3.22,4=6,72\left(l\right)\end{matrix}\right.\)

2Al+6HCl->2AlCl3+3H2

0,2-----0,6-----0,2-----0,3

n Al=0,2 mol

n HCl=0,675 mol

=>Hcl dư

=>m HCl=0,075.36,5=2,7375g

b)m AlCl3=0,2.133,5=26,7g

c) VH2=0,3.22,4=6,72l

a)

\(Zn + 2HCl \to ZnCl_2 + H_2\)

b)

\(n_{H_2} = \dfrac{2,24}{22,4} = 0,1(mol)\)

Theo PTHH : \(n_{HCl} = 2n_{H_2} = 0,1.2 = 0,2(mol)\)

c)

Ta có :

 \(n_{ZnCl_2} = n_{H_2} = 0,1(mol)\\ \Rightarrow m_{ZnCl_2} = 0,1.136 = 13.6(gam)\)

\(n_{H_2}=\dfrac{2,24}{22,4}=0,1(mol)\\ Mg+2HCl\to MgCl_2+H_2\\ MgO+2HCl\to MgCl_2+H_2O\\ \Rightarrow n_{Mg}=0,1(mol)\\ \Rightarrow \%_{Mg}=\dfrac{0,1.24}{6,4}.100\%=37,5\%\\ \Rightarrow \%_{MgO}=100\%-37,5\%=62,5\%\)

\(b,n_{MgO}=\dfrac{6,4-0,1.24}{40}=0,1(mol)\\ \Rightarrow n_{HCl}=2.0,1+2.0,1=0,4(mol)\\ \Rightarrow V_{dd_{HCl}}=\dfrac{0,4}{0,5}=0,8(l)\\ c,n_{MgCl_2}=0,1+0,1=0,2(mol)\\ \Rightarrow C_{M_{MgCl_2}}=\dfrac{0,2}{0,8}=0,25M\)

a) $n_{H_2SO_4} = \dfrac{44,1}{98} = 0,45(mol)$

$2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$

Theo PTHH : 

$n_{Al} = \dfrac{2}{3}n_{H_2SO_4} = 0,3(mol)$
$m_{Al} = 0,3.27 = 8,1(gam)$

b) $n_{H_2} = n_{H_2SO_4} = 0,45(mol)$
$\Rightarrow V_{H_2} = 0,45.22,4 =1 0,08(lít)$

c)

Cách 1 : $n_{Al_2(SO_4)_3} = \dfrac{1}{3}n_{H_2SO_4} = 0,15(mol)$
$\Rightarrow m_{Al_2(SO_4)_3} = 0,15.342 = 51,3(gam)$

Cách 2 : Bảo toàn khối lượng, $m_{Al_2(SO_4)_3} = 8,1 + 44,1 - 0,45.2 = 51,3(gam)$

Ta có: \(n_{H_2SO_4}=\dfrac{58,8}{98}=0,6\left(mol\right)\)

\(PTHH:2Al+3H_2SO_4--->Al_2\left(SO_4\right)_3+3H_2\uparrow\)

               0,4 <---  0,6    ----------->      0,2    -->   0,6

\(\Rightarrow\left\{{}\begin{matrix}m_{Al}=0,4.27=10,8\left(g\right)\\m_{Al_2\left(SO_4\right)_3}=0,2.342=68,4\left(g\right)\\V_{H_2}=0,6.22,4=13,44\left(lít\right)\end{matrix}\right.\)

a) PTHH: \(Na_2SO_3+H_2SO_4\rightarrow Na_2SO_4+H_2O+SO_2\uparrow\)

Ta có: \(n_{Na_2SO_3}=\dfrac{12,6}{126}=0,1\left(mol\right)=n_{SO_2}\) \(\Rightarrow V_{SO_2}=0,1\cdot22,4=2,24\left(l\right)\)

b) Ta có: \(\left\{{}\begin{matrix}n_{SO_2}=0,1\left(mol\right)\\n_{Ca\left(OH\right)_2}=1,4\cdot0,1=0,14\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Tạo muối trung hòa

PTHH: \(Ca\left(OH\right)_2+SO_2\rightarrow CaSO_3\downarrow+H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{CaSO_3}=0,1\left(mol\right)=n_{Ns_2SO_4}\\n_{Ca\left(OH\right)_2\left(dư\right)}=0,04\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{CaSO_3}=0,1\cdot120=12\left(g\right)\\m_{Na_2SO_4}=0,1\cdot142=14,2\left(g\right)\\m_{Ca\left(OH\right)_2\left(dư\right)}=0,04\cdot74=2,96\left(g\right)\end{matrix}\right.\)

\(n_{Na_2SO_3}=0,1\left(mol\right)\\ PTHH:Na_2SO_3+H_2SO_4\rightarrow Na_2SO_4+H_2O+SO_2\)

(mol)          0,1                              0,1             0,1       0,1

\(a.V_{SO_2}=0,1.22,4=2,24\left(l\right)\)

\(b.n_{Ca\left(OH\right)_2}=0,14\left(mol\right)\)

Do \(\dfrac{n_{OH}}{n_{SO_2}}=\dfrac{0,28}{0,1}=2.8>2\rightarrow\) Tạo muối trung hòa và Ca(OH)₂ dư 0,04(mol)

\(PTHH:Ca\left(OH\right)_2+SO_2\rightarrow CaSO_3+H_2O\)

(mol)           0,1           0,1         0,1            0,1

\(m_{Ca\left(OH\right)_2\left(du\right)}=0,04.74=2,96\left(g\right)\\ m_{CaSO_3}=12\left(g\right)\\ m_{H_2O}=0,1.18=1,8\left(g\right)\)